Use the following code snippet and try to edit the Height. You will notice that the sub-items' order is changed:
RadPropertyStore store = new RadPropertyStore();
PropertyStoreItem sizeItem = new PropertyStoreItem(typeof(System.Drawing.Size), "Size", new System.Drawing.Size(100, 25), "The size of the control in pixels.", "Layout");
store.Add(sizeItem);
this.radPropertyGrid1.SelectedObject = store;
this.radPropertyGrid1.SortOrder = SortOrder.Ascending;
this.radPropertyGrid1.PropertySort = PropertySort.Alphabetical;