How to reproduce: public partial class Form1 : Form { public Form1() { InitializeComponent(); ThemeResolutionService.AllowAnimations = false; this.radGridView1.DataSource = this.GetData(); } private DataTable GetData() { DataTable dt = new DataTable(); dt.Columns.Add("Id", typeof(int)); dt.Columns.Add("Name", typeof(string)); dt.Rows.Add(1, "\u0002x09"); for (int i = 1; i < 10; i++) { dt.Rows.Add(i, "name"); } return dt; } private void radButton1_Click(object sender, EventArgs e) { GridViewSpreadExport spreadExporter = new GridViewSpreadExport(this.radGridView1); spreadExporter.FileExportMode = FileExportMode.CreateOrOverrideFile; SpreadExportRenderer exportRenderer = new SpreadExportRenderer(); spreadExporter.RunExport(@"..\..\exported-file.xlsx", exportRenderer); } } ArgumentException with clarification similar to "'\u001f', hexadecimal value 0x1F, is an invalid character." is thrown when trying to export document containing characters which are not supported in XML document - such as some control characters like 0x00, 0x1F, 0x1B, etc. Such characters are described in the XML specification here: https://www.w3.org/TR/xml/#charsets. Although the escaped strings are not supported (see https://feedback.telerik.com/Project/184/Feedback/Details/190228 ), the library could prevent the exception and export the document successfully by skipping such characters. Workaround: remove such characters before the export. Check the following StackOverflow answer for some ideas on code for replacing the characters: http://stackoverflow.com/a/14323524/259206