Importing a document with block-level content controls from XAML causes them to become corrupt. If you scroll to a position in which the said control is only partially visible a NullReferenceException is thrown.

A possible workaround would be to initially save the document as a DOCX (just exporting it to DOCX will not fix the issue as the information is already corrupt).

Another way to reproduce this issue:

1. Create a new document and insert a Rich Text Content Control.

2. Save the document as a XAML file.

3. Reopen the XAML file.

4. Move the caret inside the Content Control.

5. Try to insert a new line by hitting Enter - no new line is added as the content control is marked as Inline Level after the import in step 3.

Case 2: 

Create a document with TOC where the content control of the TOC contains some other inlines.