When you place a DataTrigger whithin a CellTemplate, it is being ignored by RadGridView for WPF Workaround ( until fixed ) - set the ContentTemplate of the cell via Style in a static resource instead.
Indeed, it has been awhile, but we tried to find a solution that will not break the current functionality or introduce performance problems. With WPF DataGrid DataTemplate used as CellTemplate is set directly as ContentTemplate to the cell and all triggers are directly transferred. However, with RadGridView the content of the cell is set from template.LoadContent() method and is returned from the CreateCellElement method of the column. One possible scenario for a fix is to change that behavior and apply directly the template as WPF DataGrid does. However, this is a huge breaking change with CreateCellElement method is widely used. The second approach is to leave the code as it is right now, return the element from LoadContent method of DataTemplate and set the ContentTemplate property of the cell to that DataTemplate. This will cause the content to be loaded twice. Which will degrade the performance. So, as it turns out the solution is either to introduce breaking change, or degrade the performance. Both of them are against our believes and efforts to improve the controls. Our suggestion is to use the workaround by setting triggers directly to the style. We do hope you understand our concerns.
Framework limitation? But it's working in standard WPF DataGrid! It's five years already...
As it turns out this would be a framework limitation and therefore we cannot resolve it for RadGridView. I can suggest you using Style.Triggers instead.
Still not resolved (2012 Q3 release).
This Issue is not resolved in the current Version 2012_01 of the RadControls.