The following CSS will override the built-in rules to improve the icons positioning:

            div.RadWindow_Glow .rwTable .rwTitlebarControls .rwIcon
            {
                margin: 3px 5px 0 0;
            }

            div.RadWindow_Silk .rwTable .rwTitlebarControls .rwIcon
            {
                margin: 2px 5px 0 0;
            }

            div.RadWindow_Bootstrap .rwTable .rwTitlebarControls .rwIcon
            {
                margin: 6px 5px 0 0;
            }