For the time being the property can be set through the kendoWidget:
Available options can be found here - http://docs.telerik.com/kendo-ui/api/dataviz/chart#configuration-categoryAxis.weekStartDay
<script>
function pageLoad() {
var kendoWidget = $find("<%=RadHtmlChart1.ClientID%>")._chartObject;
kendoWidget.options.categoryAxis.weekStartDay = 1;
kendoWidget.redraw();
}
</script>
<telerik:RadHtmlChart runat="server" ID="RadHtmlChart1" Width="600px" Height="400px">
<PlotArea>
<Series>
<telerik:ColumnSeries Name="Product 1" DataFieldY="SellQuantity">
</telerik:ColumnSeries>
</Series>
<XAxis DataLabelsField="SellDate">
<LabelsAppearance DataFormatString="yyyy/MM/dd"></LabelsAppearance>
</XAxis>
</PlotArea>
</telerik:RadHtmlChart>