For the time being the property (http://docs.telerik.com/kendo-ui/api/javascript/dataviz/ui/chart#configuration-legend.border) can be set through the chartObject. For example:
JavaScript:
	<telerik:RadCodeBlock ID="RadCodeBlock1" runat="server">
		<script>
			function pageLoad() {
				var chart = $find("<%=PieChart1.ClientID%>");
				chart._chartObject.options.legend.border = { width: 2, color: "green", dashType: "longDashDotDot" }
				chart.repaint();
			}
		</script>
	</telerik:RadCodeBlock>
ASPX:
		<telerik:RadHtmlChart runat="server" ID="PieChart1" Transitions="true">
			<PlotArea>
				<Series>
					<telerik:PieSeries StartAngle="90">
						<LabelsAppearance Position="OutsideEnd" DataFormatString="{0} %" />
						<TooltipsAppearance DataFormatString="{0} %" />
						<SeriesItems>
							<telerik:PieSeriesItem BackgroundColor="Purple" Exploded="true" Name="Internet Explorer" Y="18.3" />
							<telerik:PieSeriesItem BackgroundColor="Orange" Exploded="false" Name="Firefox" Y="35.8" />
							<telerik:PieSeriesItem BackgroundColor="Green" Exploded="false" Name="Chrome" Y="38.3" />
							<telerik:PieSeriesItem BackgroundColor="Blue" Exploded="false" Name="Safari" Y="4.5" />
							<telerik:PieSeriesItem BackgroundColor="Red" Exploded="false" Name="Opera" Y="2.3" />
						</SeriesItems>
					</telerik:PieSeries>
				</Series>
			</PlotArea>
			<ChartTitle Text="Browser Usage for April 2012">
			</ChartTitle>
		</telerik:RadHtmlChart>